Product ID:AS GRAFFITTI REMOVER
MSDS Date:07/26/1989
FSC:7930
NIIN:01-238-4782
MSDS Number: BMZMP

ASHLAND CHEMICAL CO. DIVISION OF ASHLAND OIL, INC

COLUMBUS, OH 43216
US

Emergency Phone: 606-324-1133

Info Phone: 614-889-3333

Cage: 5A188

ATLANTA SUNDRIES INC

LITHONIA, GA 30058 US

Telephone: 404-482-4530

Cage: ATSUN

DICHLOROMETHANE (SARA III) (OSHA ACCEPTABLE CEILING

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 1-10%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

* CEILING CONCENTRATION FOR 8-HR SHIFT IS 2000 PPM FOR

RTECS: 9999999ZZ

XYLENE (SARA III) (TECHNICAL GRADE XYLENE CONTAINS 18-20%

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 75-85%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

*** PPM-STEL. IT HAS A CAS OF 100-41-4. ETHYL BENZENE IS

RTECS: 9999999ZZ

ETHYL ALCOHOL

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 1-5%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:EYE: IRRITATION. SKIN: MODERATE
IRRITATION, DERMATITIS. BREATHING: NASAL/RESPIRATORY IRRITATION,
CENTRAL NERVOUS SYSTEM EFFECTS, DEATH. SWALLOWING GASTROINTESTINAL
IRRITATION. ASPIRATION OF MATERIAL I NTO LUNGS CAN CAUSE CHEMICAL
PNEUMONITIS WHICH CAN BE FATAL. CARDIOVASCULAR STRESS.
Explanation of Carcinogenicity:METHYLENE CHLORIDE LISTED AS POTENTIAL
CARCINOGEN (2B).
Effects of Overexposure:EYE: REDNESS, TEARING. SKIN: DEFATTING.
BREATHING: DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE &
POSSIBLE UNCONSCIOUSNESS. SWALLOWING: NAUSEA, VOMITING, DIARRHEA.
Medical Cond Aggravated by Exposure:N/K SHOULD BE GROUNDED AND/OR
BONDED WHEN MATERIAL IS TRANSFERED. VAPRS ARE HEAVIER THAN AIR, MAY
TRAVEL ALONG GROUND OR MOVED BY VENT & IGNITED.

First Aid:SKIN: WASH W/SOAP & WATER. REMOVE CONTAM CLOTH. EYE: FLUSH
W/WATER, LIFTING EYELIDS OCCAS. GET MED AID. INGEST: DON'T INDUCE
VOMIT. KEEP WARM, QUIET. GET MED AID. ASPIRATION INTO LUNGS
(VOMITING) CAN CAUSE CHEM PNEUMONITIS--CAN BE FATAL. INHAL: REMOVE
TO FRESH AIR. IF BREATH DIFFICULT, ADMIN OXYGEN. IF BREATH STOPPED,
GIVE ARTIF RESP. KEEP WARM, QUIET. GET MED AID. DON'T GIVE
STIMULANTS.

Flash Point Method:TCC
Flash Point:20.0F,-6.7C
Lower Limits:1.0
Extinguishing Media:REGULAR FOAM, OR WATER FOG OR CARBON DIOXIDE OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A
FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN
FIGHTING FIRES.
Unusual Fire/Explosion Hazard:NEVER USE WELD/CUT TORCH ON/NEAR DRUM
(EVEN EMPTY) BECAUSE PROD (EVEN RESIDUE) CAN IGNITE EXPLOS. 5 GAL
PAILS & LRGR METAL CONTAINERS INCLUDING TANK CARE/TRUCK

Spill Release Procedures:SMALL: ABSORB LIQ ON PAPER, VERMIC, FLOOR
ABSORB, ETC. LRG: ELIM IGNIT SOURCE. EVAC THOSE NOT WEARING PROTECT
EQUIP. STOP SPILL, DIKE, PUMP LIQ TO SALVAGE TANK. USE ABSORB ON
REMAIN LIQ & SHOVEL INTO CNTNRS. PREVENT RUNOFF TO
SEWER/STREAM/WTR
Neutralizing Agent:N/K NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A
SPILL HAS OCCURED.

Respiratory Protection:IF TLVS OF PROD OR COMPONENT EXCEEDED,
NIOSH/MSHA AIR SUPPLIED RSPRTR ADVISED IN ABSENCE OF PROPER
ENVIRONMENTAL CONTROL. OSHA REGS PERMIT OTHER NIOSH/MSHA RSPRTR
(NEG PRESSURE) UNDER SPECIFIED CONDS. IMPLEMENT ENGINEER/ADMIN
CONTROLS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL/LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Supplemental Safety and Health

HCC:V3
Boiling Pt:B.P. Text:104F,40C
Vapor Pres:355 @68F
Spec Gravity:<1.000 @77F
Evaporation Rate & Reference:SLOWER THAN EHTER.
Percent Volatiles by Volume:100.00

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ALKALIES, THIS MATERIAL REACTS SLOWLY
WITH ALUMINUM.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.